I think the characters who look the most like their personalities would probably be Kattar and Alicia from "Damsel in the Red Dress."
Kattar is stylish and extremely beautiful, which is kind of what you'd expect from a pampered rich boy raised by a mother as beautiful as his mother is. Meanwhile Alicia is considered to look like a curvy doll, which also suits her shy, and extremely delicate nature.
Little details of their personalities of course still come up that don't seem to match their outside appearances, like Alicia's love for weird animals, drinking problem, and Kattar's love for action movies (including some pretty violent ones.) And there are also little details in Alicia's physical appearances that break away from the first level of assumptions people might make about her too, because despite looking dollish, she is on the chunkier side, extremely curvy, and she has very thick eyebrows, all things that stray her away from a cliche and make her into an individual.