Don't try and make him interesting; try and make him human.
If you make him and all the characters around him act like people, readers will notice the not talking on their own i'n the scenes he's and wonder a little. They'll also notice when other characters make a big deal out of when he does talk, they'll realise it's an unusual thing. Also having other characters react to him talking in line with their own character and how much of the reason behind the selective mutism they know will help give pieces to the audience about why. Say a really emotionally intelligent character hears him talk, they could hug him, or be overjoyed, encouraging and congratulating even though it was only a word or two, while a less aware or more bitter character could mock him "finally he speaks, and for nothing" and then everything in between.
Also try and put yourself in your character's shoes. You are now the traumatised person with selective mutism. You are now trying to exist and communicate with people without speech and sometimes it just gets too much and you freeze. From the outside it looks like you are doing nothing, but what's happening inside? Panic? Fear? Guilt? Anger? Frustration? Turmoil? Chaos? Or rather complète dissociation as you have a kind of outer body experience to protect yourself. Why don't you want an identity? What do you do other than not speaking to accomplish that? How is what you're doing helping you achieve that goal?
Just keep asking questions until you know that character well and then plop them in an environment where other characters reactions to their actions tells the reader a lot.