I do all of the character ink and paint in Kamikaze. It's all done digitally. First thing I do is ink everything. Because of our 'animated TV show' style I really don't get to play with line weight that often. It's kind of a bummer, but there you have it.
Then I head into doing the flats...
Followed by the fun bit - SHADING!! First I lay down the rough areas of shading in a really obnoxious color. It's ugly on purpose so I don't get distracted by fussing with color.
Then I lay down some lines for fill so all the edges are crisp and clean. This is also done in an obnoxious color so I stay focused on getting the shape down.
At this point I pull up a shade guide that I made for each of the characters. They're messy and kinda unorganized but they look a bit like this:
Then I take the colors and fill them in to what they should be.
The artwork then gets a bit of color correction and further shading with gradients and such in compositing. It's a really long process, especially with crowds...ohgodthecrowds...but that's how it's done on our end for character work