Ample pre-planning, and multiple coats. 
I think part of gaining experience with physical media is learning to wing it/fix mistakes on the fly, but if you're not at that point yet, you definitely need to plan out what the picture will look like before you even pick up a brush. Do a sketch first; including shading and highlights like @NickRowler suggested, so you know where all the colors are going to go.
Now, for even coverage, there is no way around just going over the painting again and again with multiple coats of paint. ^^; Acrylics are basically liquid plastic, and all but the darkest colors tend to spread very thin...fortunately, they also dry pretty fast, so you can totally do a coat, wait 5-10 minutes, and then do another coat, and repeat until the colors are as solid as you want.
Here's an example painting: the quality of the photo isn't great, but you can see that most of the colors are pretty solid.

HOWEVER, you can definitely see spots of old color underneath the yellow-- despite multiple coats, that color in particular is so thin, it just can't compete. ^^; I let it be in those spots, but for most of this woman's face and figure I primed/mixed it with white to help it cover properly.
Tbh, I think a lot of the colors you made are actually perfect matches for what's in the screenshot...only maybe it's hard to tell because you kind of just threw them onto the canvas without any sort of technique in mind...? ^^;
Like, that skin color is fine...but there aren't enough coats, and the shape of her face has no definition or shading of any kind. Similarly, I see what you tried to do with that dark shadow between the layers of Jinx's hair...but you didn't paint a shadow, and you didn't really paint hair; you kinda just smeared a dark blob on top of a bunch of other blobs...
Real talk-- @kyupol had a point when it comes to skill level. I don't know what kind of result you expect when it looks like you're painting with your toes...color accuracy and solidity are honestly the least of your issues there; fixing those relatively minor things wouldn't make the painting look much better. I really think you need to get some smaller brushes and focus on technique first; build some muscle memory and dexterity when it comes to just making shapes on the canvas; then go back and perfect your colors.